A DoE–TOPSIS meta-model for parametric optimization of silicon carbonitride (SiCN) thin film deposition process

Dhruva Kumar, Partha Protim Das, Shankar Chakraborty, Ashis Sharma, Bibhu P. Swain
2019 Journal of the Brazilian Society of Mechanical Sciences and Engineering  
Silicon carbonitride (SiCN) thin films were deposited on p-type Si(100) substrate by thermal chemical vapour deposition process using SiC and Si 3 N 4 nanopowder as the source, and mixture of N 2 and H 2 as precursor gases. For the experimental design, Taguchi's L 25 orthogonal array was used considering H 2 flow rate, N 2 flow rate and deposition temperature as the input deposition parameters, while taking into account, I D /I G ratio, hardness and Young's modulus as the responses. Design of
more » ... ponses. Design of experiments integrated with technique for order of preference by similarity to ideal solution (TOPSIS) method was applied to develop a corresponding meta-model so as to obtain the optimal parametric combination of the deposition process with respect to the computed TOPSIS score. It was found that optimal parametric combination of H 2 flow rate as 60 sccm, N 2 flow rate as 100 sccm and deposition temperature as 1300 °C results in improved values of I D /I G ratio, hardness and Young's modulus. The microstructure, chemical bonding and mechanical properties of SiCN thin films were characterized using Atomic force microscopy, Raman spectroscopy and nano-indentation techniques. As the developed meta-model is solely based on the analysis of the data obtained from experimentation, it is more practical and immune of introducing any additional parameter in the analysis. Moreover, the developed surface plots will further help the process engineer in selecting the most suitable combination of deposition parameters for achieving desirable responses.
doi:10.1007/s40430-019-1796-6 fatcat:xcryq3dvqrdn5iv7asv4xnf55a