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The compounds KHgAs, KHgSb and KZnAs were prepared and their structures determined by powder and single crystal data. The compounds crystallize in a modified Ni2In-type structure, space group P63/mmc-D46h. The cell parameters are: KHgAs a = 450.6pm, c = 997.6pm, c/a = 2.21; KHgSb a = 478.4pm, c = 1022.5pm, c/a = 2.14; KZnAs a = 423.0pm, c = 1023.4pm, c/a = 2.42.doi:10.1515/znb-1980-0127 fatcat:p2j6bupyljfclmcqh4vjph4euq