Crevice corrosion of carbon steel was investigated in different exposure environments by performing coupon exposure and electrochemical tests. The extent of corrosion on the bold surface of a carbon steel crevice coupon was more severe at 80 • C than at 21 • C, in aerated rather than dearated solutions, and with γ-radiation present. In contrast to normal crevice corrosion, we observed 'inverse crevice corrosion' behavior, the phenomenon where it is the corrosion on the bold surface that is

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... erated when coupled, rather than that on the crevice surface. The coupling current measured between a crevice and a bold electrode in an electrochemical cell was also negative. This inverse crevice corrosion behavior is attributed to a significantly lower metal cation dissolution capacity of the small occluded water volume in the crevice, compared to that of the bulk water volume over the bold surface. The reduction in dissolution capacity results in faster and earlier formation of a protective oxide layer. Corrosion of the bold and crevice surfaces evolves at different rates, leading to galvanically accelerated corrosion of the bold surface. The effect of γ-radiation on corrosion evolution in different solution environments leading to inverse crevice corrosion is discussed. CS Quartz Water droplet Polyester holder ) unless CC License in place (see abstract). ecsdl.org/site/terms_use address. Redistribution subject to ECS terms of use (see 207.241.231.83 Downloaded on 2018-07-20 to IP ) unless CC License in place (see abstract). ecsdl.org/site/terms_use address. Redistribution subject to ECS terms of use (see 207.241.231.83 Downloaded on 2018-07-20 to IP C542 Journal of The Electrochemical Society, 164 (9) C539-C553 (2017) ) unless CC License in place (see abstract). ecsdl.org/site/terms_use address. Redistribution subject to ECS terms of use (see 207.241.231.83 Downloaded on 2018-07-20 to IP ) unless CC License in place (see abstract). ecsdl.org/site/terms_use address. Redistribution subject to ECS terms of use (see 207.241.231.83 Downloaded on 2018-07-20 to IP ) unless CC License in place (see abstract). ecsdl.org/site/terms_use address. Redistribution subject to ECS terms of use (see 207.241.231.83 Downloaded on 2018-07-20 to IP ) unless CC License in place (see abstract). ecsdl.org/site/terms_use address. Redistribution subject to ECS terms of use (see 207.241.231.83 Downloaded on 2018-07-20 to IP