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The Activity Coefficients of Electrolytes with Particular Reference to Aqueous Mixtures of 2:2 with 1:1 Electrolytes

1971
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Proceedings of the Royal Society A
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Muller's method for the exact solution of the Poisson-Boltzman equation (P.B.M.) has been used to produce tables for general application, for the potential, for the activity coefficients and for the osmotic coefficients of 2:2 electrolytes in aqueous solutions, both alone and in the presence of strong 1:1 electrolyte. The activity coefficients for 2:2 electrolytes were found to be equivalent to those derived by Bjerrum's method of ionic association up to values of s/a = z2e2jekTa of about 9.

doi:10.1098/rspa.1971.0047
fatcat:ta4bp2uivrcszmrqqjrq55touu