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By reaction of [(π-H5H5)(CO)2Mn≡C-C6H5]BCl4 with NaRe(CO)5 a new type of complex is obtained. It crystallizes in the monoclinic space group P21/c, Z = 4, a - 1115(1), b= 1464(1), c= 1657(2) pm, β= 136.79(8)°. Structure determination reveals a binuclear complex, the Mn-Re bond (281.7(3) pm) of which is bridged by the a-carbon atom of a phenylketenyl group (Mn-C 221(3), Re-C 224(3) pm) and semi-bridged by a CO group (Mn-C 187(4), Re-C 254(4), Mn-C-0 160(3)°).doi:10.1515/znb-1980-0119 fatcat:d7vftj5ghzgvfn32k7i2vilbqa