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The chlorothionitrene complex [Cl4Mo(NSCl)]2 reacts with N,N,N′-tris(trimethylsilyl)benzamidine in THF solution to form the heterocyclic complex [MoCl2(NSN) · 2 THF]2, which contains the [NSN]4-unit. The compound is characterized by IR spectroscopy and by an X-ray structure determination (Space group P2,/c, Z = 2, 1504 observed unique reflexions, R = 0.044. Lattice dimensions at 19°C: a = 1176.0(1), b = 1108.6(4), c = 1227.3(3) pm, β = 118.25(1)°). The compound forms centrosymmetric moleculesdoi:10.1515/znb-1989-1029 fatcat:2o2krf4ib5dunkjcaohr3ru3xq