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<div> <p>The results of our combined experimental (FTIR, XPS, HAADF-STEM, EXAFS) and density functional theory study reveal that Pd ions in zeolites, previously identified as Pd<sup>+3</sup> and Pd<sup>+4</sup>, are in fact present as super electrophilic Pd<sup>+2</sup> species (ion pairs with the negatively charged framework oxygens). In this contribution we re-assign the spectroscopic signatures of these species, discuss the unusual coordination environment of "naked" (ligand-free)doi:10.26434/chemrxiv.7789454.v1 fatcat:bxbw56ercnhutouij6nex7ngea