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A superstructure optimization approach to power-to-methane process design that includes heat integration is presented. Carbon dioxide from biogas plants is considered as carbon source. The superstructure includes 13 alternative process technologies in seven layers for power-to-methane processes at their current stage of development. For different scenarios, the most efficient process in terms of product chemical exergy and the most cost-effective process in terms of capital and total annualdoi:10.25673/35019 fatcat:siqy7yvlbfgl7lbhspqipkathu