Electrochemical hydrogenation of a homogeneous nickel complex to form a surface adsorbed hydrogen-evolving species

Daniel J. Martin, Brian D. McCarthy, Carrie L. Donley, Jillian L. Dempsey
2015 Chemical Communications  
A Ni(ii) complex with nitrogen and sulfur donor ligands degrades electrochemically in the presence of acid in acetonitrile to form an electrode adsorbed film that catalytically evolves hydrogen.
doi:10.1039/c4cc08662g pmid:25470993 fatcat:ncpkf72jb5gtdfegzzueh7bb2m