A Multi-Scale Approach to Understanding CO2-Solvent Systems for the Development of CO2 Capture Technologies

Anita S. Lee
2018
CO2 capture from a coal-fired power plant is a difficult problem that is costly due to the high energy demands of the process. Given the existing and well-understood processes for pre-combustion CO2 removal through physical absorption and post-combustion ue gas acid gas treating, developing new solvents with lower energy demands has potential to reduce CO2 capture costs of these processes. In this work, we use analytical and computational techniques to understanding of CO2-solvent systems at a
more » ... lvent systems at a molecular and process scale. This multi-scale understanding of solvent-CO2 systems will guide the design of new solvents for low cost CO2 capture. At the molecular level, CO2-solvent interactions were studied to understand the role of the solvent and identify solvent molecular properties that could be used as descriptors and/or tuning parameters of the interactions. A Density Functional Theory study of CO2-amine solvents for post-combustion capture showed the reaction energy to form bicarbonate and carbamate products were stabilized for amines functionalized with electron donating groups and destabilized with electron withdrawing groups. Additionally, amine electronegativity was determined to be a good descriptor of the amine-bicarbonate reaction energy, which could be tuned with the choice of functional group and degree of amine functionalization. CO2 interactions with pre-combustion capture physical solvents, hydrophobic CO2-philic oligomers and 1-alkyl-3-methylimidazolium based ionic liquids, were characterized using Raman spectroscopy. Additionally, a technique to quantify solubility of CO2 in physical solvents using the Raman spectra was developed and showed CO2 solubility to correlate with molecular weight of the solvent. Aspen Plus simulations coupled with a genetic algorithm were used to understand the potential impact of solvent selection on the post-combustion CO2 capture p [...]
doi:10.1184/r1/6714362 fatcat:55hjhrc4wreutggnwzw5ye4u3q