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Mechanochemical synthesis: route to novel rock-salt-structured high-entropy oxides and oxyfluorides
2020
A facile mechanochemical reaction at ambient temperature was successfully applied to synthesize novel single-phase rock-salt-structured high-entropy oxides, containing five, six and seven metal elements in equiatomic amounts. This synthesis approach overcomes the limitations of the commonly known synthesis procedures, which would result in multiple-phase compounds. Redox-sensitive elements, such as Fe$^{2+}$ and Mn$^{2+}$, can now be considered. The corresponding single-phase Li-containing
doi:10.5445/ir/1000125242
fatcat:72ht6gzumbfj3o6pyajubdrhce