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We outline a simple protocol that accesses directly unprotected secondary amines by intramolecular C−N bond forming dearomatization or aryl C−H amination. The method is dependent on the generation of a potent electrophilic aminating agent released by in situ deprotection of O-Ts activated N-Boc hydroxylamines.doi:10.1021/jacs.7b07830.s001 fatcat:h5jk6evr75fejhma2qhnxsazre