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Triphenylgermyl-lithium in diethyl ether/THF did not react with Al2Me6 to form [(Ph3Ge)AlMe3]- Li(THF)n. Addition of TMEDA to this solution yielded crystalline Ph3GeLi(THF)TMEDA. The reaction of Ph3GeLi in diethyl ether/hexane solution with H3Al-NMe3 in diethyl ether/THF generated [Ph3GeAlH3]Li(THF)4 while the reaction with Me2AlCl led to Ph3GeAlMe2(OEt2) and the trigermyl-aluminate [(Ph3Ge)3AlMe]Li. The analogous aluminate [(Ph3Ge)3AlH]Li(THF)3 was obtained by reacting LiGePh3 withdoi:10.1515/znb-2009-11-1220 fatcat:irimu6hkyrarzkjx3xzfoybpju