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The cadmium sulfide (CdS) films were prepared on glass substrates by chemical bath deposition method using aqueous solutions of cadmium chloride, thiourea, sodium citrate (complexing agent) and ammonia (pH regulator). A theoretical calculation of the boundary conditions of the formation of cadmium sulfide and cadmium hydroxide in the citrateammonia system was performed in this work. The composition, structure, optics and morphology of the synthesized CdS semiconductor films were experimentallydoi:10.32434/0321-4095-2019-123-2-39-46 fatcat:5t6fzp7dv5d55gc6jzdsxuvjtu