Rio Grande do Norte has mountain formations with edaphoclimatic conditions different from those predominating in the state, presenting deeper,acid soils, and milder climate. Among these formations, is the Santana mountain range, which is part of the Serra do Martins Formation. The objective of this work was to interpret the pedogenesis of the representative soils of the Santana mountain range through morphological, physical, and chemical characterizations of soil profiles and evaluate the

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... evaluate the effect of these attributes on the distribution of pedological forms along the landscape using multivariate analysis. Morphological, physical, and chemical analyses of seven soil profiles of the Santana mountain range were performed. The soils were classified according to the Brazilian Soil Classification System and the data subjected to multivariate analysis. The representative soil classes found were: LATOSSOLO AMARELO Distrófico argissólico; LATOSSOLO AMARELO Eutrófico argissólico; NEOSSOLO QUARTZARÊNICO Órtico típico; NEOSSOLO LITÓLICO Eutrófico fragmentário; NEOSSOLO REGOLÍTICO Eutrófico típico and CAMBISSOLO HÁPLICO Tb Eutrófico léptico. According to the analysis of the morphological attributes, the parent material had great influence on the formation of the different soil classes found in the Santana mountain range. The soil textural classes varied from sand to sandy clay loam. According to the analysis of the chemical attributes, the soil profiles presented acid reaction, great variation of base saturation, and low electrical conductivity. The multivariate analysis established groups of representative soil profiles of the Santana mountain range through the distinction of their physical and chemical attributes, mainly of subsurface diagnostic horizons.