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Time-resolved resonance Raman (TR3) and absorbance difference studies of the excited states of Cu(TPP) (TPP 5,10,15, have been carried out with < 10 ps times resolution in THF and pyridine solvents. In THF the distinctive transient Raman bands in the u2 and/4 regions, previously observed with ns laser pulses, grow in the first 55 ps before decaying in 100's of ps. The AA spectra also show biphasic decay. This behaviour is associated with attack by solvent on the 4-coordinate excited state todoi:10.1155/1999/82824 fatcat:nbj5jvkjfne65p5y7g5nbbbomq