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A highly versatile cobalt-catalyzed hydrosilylations of alkynes is reported. Near-perfect regiocontrol/stereocontrol was induced by the choice of the ligand: bidentate phosphines afforded (E)-β-vinylsilanes; α-vinylsilanes formed with bipyridine ligands.doi:10.1039/c8cc07267a pmid:30310911 fatcat:pajlzfgymnbnnkzw2wnqkbig44