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Ionic liquid/PVDF-HFP based electrolyte is one of the promising solid state electrolyte for energy storage devices. It is known that additional amount of propylene carbonate (PC) or Ethylene carbonate (EC) can improve the conductivity of the electrolyte though the ion concentration is diluted. Both dielectric spectroscopy and time domain method are employed to characterize the segmental dynamics of the polymer matrix and the charge dynamics of ionic in the electrolyte over a broad temperaturefatcat:vlotrc6cbbh4daodvzjxo4mo5i