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Present communication reports the experimental values of the dielectric relaxation time () of 4 Methoxyaniline, 4 Ethoxyaniline, 2 Nitroaniline, 2 Chloro, 4 Nitroaniline, 2,6 Dichloroaniline and 2 Methoxy, 3 Nitroanilinein dilute solution of benzene at wavelength 3.13 cm in the microwave region. The measurements have been made at 293, 303 and 313 0 K, in order to calculate the free energy of activation for dipole orientation process (F). The experimental values of have been correlated withdoi:10.22147/jusps-b/290202 fatcat:iavqfmeloncgbfapr2sllfjo5u