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Source of material: Brass-colored LÌ5[(Lii_jtNii)N]3 was obtained during our re-investigation (see ref. 1) of the substitution series LÌ2[(Lìi_xNì,)N] (see ref. 2). Single crystals were grown from a LisN/Ni-mixture (molar ratio 1:1 ) in a Ni-crucible (N2,1 atm) by rapid cooling from 1173 K. The crystal structure of LÌ5[(Lii-xNix)N]3 (χ = 0.77) is an ordered defect variant of the LÌ2[LiN] type structure (see ref. 3). Li-vacancies within the original LÌ2N-layers result in layers of compositiondoi:10.1524/ncrs.1918.104.22.168 fatcat:d6r7ug6hubcivmdex42iaxkywm