Preconcentration, determination and speciation of iron by solid-phase extraction using dimethyl (E)-2-[(Z)-1-acetyl)-2-hydroxy-1-propenyl]-2-butenedioate

Gholamreza Khayatian, Shahed Hassanpoor, Farough Nasiri, Amin Zolali
2012 Química Nova  
Recebido em 2/6/11; aceito em 24/9/11; publicado na web em 6/12/11 A new sensitive and selective procedure for speciation of trace dissolved Fe(III) and Fe(II), using modified octadecyl silica membrane disks and determination by flame atomic absorption spectrometry was developed. A ML 3 complex is formed between the ligand and Fe(III) responsible for extraction of metal ion on the disk. Various factors influencing the separation of iron were investigated and the optimized operation conditions
more » ... re established. Under optimum conditions, an enrichment factor of 166 was obtained for Fe 3+ ions. The calibration graph using the preconcentration system for Fe 3+ was linear between 40.0 and 1000.0 mg L -1 .
doi:10.1590/s0100-40422012000300018 fatcat:p3drk6jxafewdfw75cdpcf7ida