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We have investigated the H/D exchange reaction between heavy water and an ionic liquid, 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF 4 ]), throughout the whole concentration region as a function of D 2 O mol% at room temperature. We expected that the extent of the H/D reaction would increase linearly with increasing content of D 2 O, but the results show an extended N-shaped behavior having a small maximum at around 40 mol% and the reaction becomes very slow at a specificdoi:10.4236/ojpc.2011.13010 fatcat:pqlirvvhofanvhhzcqjpk2w624