Asymmetric retro-[1,4]-Brook rearrangement of 3-silyl allyloxysilanes via chirality transfer from silicon to carbon

Ya Wu, Hua Chen, Wenyu Yang, Yu Fan, Lu Gao, Zhishan Su, Changwei Hu, Zhenlei Song
2019 RSC Advances  
Asymmetric retro-[1,4]-Brook rearrangement of 3-silyl allyloxysilanes has been developed involving Si-to-C chirality transfer, which is diastereoselective without loss of enantiomeric excess.
doi:10.1039/c9ra05482k fatcat:sffqma2mpjf6ffygch4dkeshw4