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We report a formalism that connects thermodynamics and transport properties such as viscosity and diffusion coefficient which has been used to calculate the concentration dependence of free energy of mixing, concentration-concentration fluctuations in the long wavelength limit and concentration dependence of diffusion and viscosity in Cu-Sb and Cu-Sn binary liquid alloys at 1190K and 1400K respectively with aid of size effect and no size effect. Our calculations show that a reasonable degree ofdoi:10.3126/bibechana.v12i0.11781 fatcat:mg7lgx3g4vd6fmkuxsq7xnvgny