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To develop advanced materials using metal complexes, it is better to prepare metal complexes contained in composite or hybrid films. To achieve this purpose, we synthesized ruthenium complexes with dihalogen-substituted benzendithiolate ligands, [(η 6 -C 6 Me 6 )Ru(S 2 C 6 H 2 X 2 )] (X = F, 3,6-Cl, Br, 4,5-Cl), 1b-1e. We also investigated preparation of 1c or 1e containing polysiloxane composite films and their reactivity to CO gas. All ruthenium complexes 1b-1e reacted with CO gas, anddoi:10.3390/molecules23040845 pmid:29642463 fatcat:xcscohd3frh5rcc7rzzfvwnj5a