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Cu 6 PS 5 Br compound belongs to the large family of complex chalcohalides crystallizing in the argyrodite structures. The main peculiarity of the copper-containing argyrodites is high ionic conductivity of Cu + ions, which makes it possible to use as the functional electronic materials. In the present study, the crystal structure of Cu 6 PS 5 Br argyrodite have been analyzed and described using the superspace symmetry concept. The program operating under the Maple environment and suitable fordoi:10.15407/spqeo21.02.134 fatcat:astyof7xpjdttci6qaqxjoeqjm