Enantioselective Total Synthesis of (–)-Myrifabral A and B

Brian M. Stoltz, Tyler Fulton, Anthony Chen, Michael D. Bartberger
2020 Chemical Science  
A catalytic enantioselective approach to the myrioneuron alkaloids (–)-myrifabral A and (–)-myrifabral B is described. The synthesis was enabled by a palladium-catalyzed enantioselective allylic alkylation, that generates the C(10) all-carbon quaternary...
doi:10.1039/d0sc01141j fatcat:etvpa2vivfhshfahmruiqizxge