Effect of impurities on cathodoluminescence of tridymite and cristobalite

Masahiro KAYAMA, Hirotsugu NISHIDO, Kiyotaka NINAGAWA
2009 Journal of Mineralogical and Petrological Sciences  
Cristobalite and tridymite in andesite and obsidian exhibit bright blue emissions in color cathodoluminescence (CL) images. CL spectra of cristobalite and tridymite show emission bands at 400 and 430 nm, respectively. Their CL intensity decreases with an increase in the electron irradiation time, similar to the shortlived blue luminescence reported in hydrothermal quartz. The reduction rate of the CL intensity of hydrothermal quartz is small as compared to cristobalite and tridymite. The
more » ... idymite. The initial CL intensity of both minerals immediately after the electron irradiation is positively correlated with the Al 2 O 3 content. This suggests that the blue emissions of cristobalite and tridymite can be attributed to the [AlO 4 /M + ] 0 defect center (M: H + , Li + , Na + , and K + ). The electron irradiation of cristobalite and tridymite diffuses the monovalent cations of H + , Li + , and Na + and destroys their crystal structure, resulting in shortlived blue luminescence. The CL intensity after 600 s of electron irradiation depends on the K 2 O impurity content. In contrast to other monovalent cations, the K + cation is not diffused because of its large ionic radius. The CL emissions of cristobalite and tridymite after 600 s of electron irradiation can be attributed to the [AlO 4 /M + ] 0 defect (M: K + ). CL images of cristobalite in obsidian from Utah, USA, show a heterogeneous distribution of CL intensity, with oscillatory CL zoning on the rim and radial lathshaped textures with bright CL superimposed on weak luminescence background. This implies that lathshaped textures with bright emissions might have crystallized from rhyolitic magma at temperatures higher than the recrystallization temperature minerals in the other areas.
doi:10.2465/jmps.090620a fatcat:hmjyltlsajhmdpphejzy53sy5e