Synthesis, Characterization and Luminescence of Silver(I) and Gold(I) Complexes Bearing a Diethyl Acetal Functionalized N-Heterocyclic Carbene

Sebastian Leitner, Manuela List, Uwe Monkowius
2011 Zeitschrift für Naturforschung. B, A journal of chemical sciences  
1-(2,2ʹ-Diethoxyethyl)-3-methyl-imidazolium bromide, 1, has been prepared and used as a precursor for the synthesis of the corresponding silver bromide complex [(NHC)2Ag][AgBr2], 2. Transmetallation of 2 with (tht)AuBr (tht = tetrahydrothiophene) yields (NHC)AuBr, 3. The solid-state structures of 2 and 3 have been determined by single-crystal X-ray diffraction revealing a loose aggregation of the complexes by weak metal-metal interactions. Due to the presence of these contacts, both complexes
more » ... s, both complexes are emissive in the solid state.
doi:10.1515/znb-2011-1210 fatcat:zcyoyjsjj5f4nhv7s3en6bmh3q