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AbstractA first effort employing a range of polar-group functionalized phosphines (L 1 –L 7 ) to design mononuclear Rh(I) compounds of [Rh(quin-8-O)(CO)(L)] (quin-8-O = 8-hydroxy quinolate) is described. The reaction of a Rh(I) precursor [Rh(μ-Cl)(CO)2]2 with 8-hydroxyquinoline in the presence of a base followed by phosphines (L 1 –L 7 ) produced only a single isomer of [Rh(quin-8-O)(CO)(L)] compounds (1–7) with pendant, i.e. non-bonded, polar-groups (includes carboxyl, hydroxyl and formyl). Adoi:10.2478/s11532-009-0108-x fatcat:ohvqfhnqlffe7lyz4dbzeoeqqu