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<div><div><div><p>Anti-Markovnikov additions to alkenes have been a longstanding goal of catalysis, and anti-Markovnikov addition of arenes to alkenes would produce alkylarenes that are distinct from those formed by acid-catalyzed processes. Existing hydroarylations are either directed or occur with low reactivity and low regioselectivities for the linear alkylarene. Herein, we report the first undirected hydroarylation of unactivated alkenes with unactivated arenes that occurs with highdoi:10.26434/chemrxiv.7825844 fatcat:hpt6ourn6ngyvgjhvsvtgkjq4q