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<p>Herein, we present a new concept for the hydroacylation of alkenes employing amides in a metal-free regime, proceeding by an entirely new mechanism and offering orthogonal reactivity to the conventional, metal-catalysed alternatives. </p>doi:10.26434/chemrxiv.7265519.v1 fatcat:cqyqjzeluzfzzowpd5ciinreza