Mode coupling and polar nanoregions in the relaxor ferroelectricPb(Mg1/3Nb2/3)O3

S. Wakimoto, C. Stock, Z.-G. Ye, W. Chen, P. M. Gehring, G. Shirane
2002 Physical Review B (Condensed Matter)  
We present a quantitative analysis of the phonon lineshapes obtained by neutron inelastic scattering methods in the relaxor ferroelectric Pb(Mg1/3Nb2/3)O3 (PMN). Differences in the shapes and apparent positions of the transverse acoustic (TA) and transverse optic (TO) phonon peaks measured in the (300) and (200) Brillouin zones at 690 K are well described by a simple model that couples the TA and soft TO modes in which the primary parameter is the wave vector and temperature-dependent TO
more » ... th Gamma(q,T). This mode-coupling picture provides a natural explanation for the uniform displacements of the polar nanoregions, discovered by Hirota et al., as the PNR result from the condensation of a soft TO mode that also contains a large acoustic component.
doi:10.1103/physrevb.66.224102 fatcat:ttm6r4mxd5fw7gpwpgpzzrlrzy