In order to realize designed synthesis, understanding the formation mechanism of zeolites at an atomic level has long been aspired, but remains challenging due to the fact that knowledge of atomic configurations of the species formed during the process is limited. We focus on a synthesis system that crystallizes <b>CHA</b> zeolite from <b>FAU</b> zeolite as the sole source of tetrahedral atoms of Si and Al, so that end-to-end characterization can be conducted. Solid-state ²⁹Si MAS

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... is followed by high-throughput computational modeling to under-stand how atomic configurations changed during the interzeolite conversion. This reveals that the structural motif commonly found in <b>FAU</b> and <b>CHA</b> is not preserved during the conversion; rather, there is a specific rearrangement of silicates and aluminates within the motif. The atomic configuration of <b>CHA</b> seems to be influenced by that of the starting <b>FAU</b>, considering that <b>CHA</b> synthesized without using <b>FAU</b> results in a random Al distribution. A Metropolis Monte-Carlo simulation combined with a lattice minimization technique reveals that <b>CHA</b> derived from <b>FAU</b> has energetically favorable, biased atomic locations, which could be a result of atomic configurations of the starting <b>FAU</b>. These results suggest that by choosing the proper reactant, Al placement could be designed, to enhance targeted properties of zeolites for catalysis and adsorption.