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Polymerization of Cyclic Esters of Phosphoric Acid
1976
Pure and Applied Chemistry
Highmolecularweightpolyestersof phosphoric acid,havebeenpreparedwithasequenceof atoms inthe main chain similar to that in naturally occuring polymers, teichoic acid or nucleic acids. Although the five and six-membered cyclic esters of phosphoric acid polymerize readily, such as with anionic or cationic initiation, the polymerization degrees are low because of an extensive chain transfer to monomer which competes successfully with chain propagation. Polymerization of the six-membered esters is
doi:10.1351/pac197648030363
fatcat:x4ku6serergobpdpwbttqxzwo4