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Using experimental methods and CSD data for investigating the products of the reaction between 2-((2-aminoethyl)amino)ethanol with CdI2 and CdI2/HgI2-mixtures
The binding modes of 2-((2-aminoethyl)amino)ethanol-based ligands were explored using the Cambridge Structural Database (CSD). To extend this field, a new cadmium complex containing 2-((2-aminoethyl)amino)ethanol (AEAE), [Cd(AEAE)2][Cd(AEAE)2]′[CdI4]2 (1), was prepared and characterized by spectroscopic methods and single-crystal X-ray diffraction. The reaction of AEAE with a 1:1 mixture of CdI2 and HgI2 was also investigated. The complex, [Cd(AEAE)2][I2Hg(μ-I2)2HgI2] (2), was synthesized anddoi:10.6084/m9.figshare.4738537.v1 fatcat:ddnoo2lk2jghplmnmlxlx4iau4