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The rotational spectra of eight isotopomers of the propene * SOz complex have been observed with a Fourier transform microwave spectrometer. The rotational constants of the normal species are A=4269334 MHz, B= 1577.2661 MHz, and C= 1469.6335 MHz. The structure of the complex was derived from least-squares fitting of the 24 moments of inertia. It has a stacked, near-parallel planes configuration. The distance between the centers of mass of the two monomers is 3.26(5) A. The sulfur atom isdoi:10.1063/1.466987 fatcat:r37byybfpvhmhp76yptnrd7sdq