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In this paper four assumptions are made : (1) Pauling's relation (2) Bond order conservation, (3) An approximation for the potential energy along the reaction coordinate and (4) a symmetry principle. The main results which follow are : (a) An expression for the bond order of the transition state, a result which is compared with potential energy surfaces, BEBO and Marcus' theories. (b) A theoretical fit for (nonlinear) Bronsted plots over a mild range of ApK. In addition, other theories whichdoi:10.1039/f29787400388 fatcat:kljo3hw4nvhllmg6ovrhjo3ix4