The Effect of Additional Elements on the Interfacial Structure and Strength at the Solder Joint between Sn-Ag-X Solder and Electroless Ni-P Plating
無電解Ni‐PめっきとSn‐Ag系はんだの継手強度と接合界面構造におよぼす各添加元素の影響

Yuunosuke NAKAHARA, Kazuo HIRA, Ryuuji NINOMIYA, Michihiro TAGAMI, Mikio SUGAI, Shinichi NAKATA
2003 QUARTERLY JOURNAL OF THE JAPAN WELDING SOCIETY  
The joint strength and the joint interfaces between electroless Ni-P plating and Sn-Ag solders ,as replacement solders for the eutectic Sn-37 Pb, were investigated. The joint strength between Cu plated by electroless Ni-P and Sn-3.5 Ag and Sn-3.5 Ag-(8, 9, 10) In decreased after annealing at 373 K, 398 K and 423 K. The effect of Zn addition to Sn-3.5 Ag and Sn-3.5 Ag-8 In on the joint strength and thickness of reaction layers was investigated. The joint strength of as-joined interfaces between
more » ... n-3.5 Ag and Sn-3.5 Ag-8 In and electroless Ni-P plating increased by 1 % Zn addition and decrease of the joint strength was inhibited by 1 % Zn addition after annealing. The joint interface between Sn-Ag solders and electroless Ni-P plating consists of Ni x -Sn y and P-rich reaction layers. It was found that the decrease of the joint strength relates to the growth of these reaction layers. The growth of these reaction layers is inhibited by 1 % Zn addition.
doi:10.2207/qjjws.21.116 fatcat:f64qwnoel5hkrjon5ax4z43xvq