Synthesis, spectral characterization and ligation behaviour of phenylmercury(II) 0, 0' -dialkyl/ alkylene dithiophosphates

Sanjay K. Srivastava, Surachna Sihare, Yogesh Pandey
2006 Zenodo  
School of Studies in Chemistry, Jiwaji University, Gwalior-474 011, Madhya Pradesh, India E-mail : Chemistry Department, Bipin Behari (P.G.) College, Jhansi, Uttar Pradesh, India Manuscript received 18 January 2006, accepted 6 March 2006 The phenylmercury(Il) complexes having composition [C6H5Hg{S(S)P(OCH2CH20CH2)2} ], [C2H5Hg{S(S)POCH2C(CH2)2CH20}] and [C2H5HgS(SJPOCH2C(CH3)2CH{CH(CH3)2}Ql were prepared by the reaction of phenylmercury(ll) acetate with NH4 salt of 0,0'
more » ... kyl/alkylene dithiophosphate in absolute methanol at room temperature.The complexes were characterized by their analytical data, IR, 1H and 31p NMR spectra. Ligation behaviour of the complexes has been established by reacting them with Cdl2, AgOCOCF 3, AgOCOCCJ3 , AgSCN, HgCI2, Hg(OCOCCI3)2, Hg(OCOCF3)2 and Hg(SCN)2• The bimetallic adducts were formed through the coordination of the sulfur atom of phenylmercury(I)) 0, 0 -dialkyllalkylene dithiophosphate to the soft metal acceptors.
doi:10.5281/zenodo.5837751 fatcat:ai7iigapzbh7haiuwefzdm6asm