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NEW HETEROCYCLIC BIVALENT TIN AND GERMANIUM SPECIES (SCHIFF'S BASE)M(II) (M = Ge, Sn) AND RELATED METALLANETHIONES AND -SELONES
1997
Main Group Metal Chemistry
The syntheses of new stable bivalent homoleptic germanium and tin species L 2 M ( L 2 = (R,R)-(-)-N,N'bis(3,5-di-ieri-salicylidene)-1,2-cyclohexanediamine, Μ = Ge (1), Μ = Sn (2) ; l_ 2 = N,N'bis(salicylidene) ethylenediamine, Μ = Ge (3), Μ = Sn (4) ; L 2 = N-methyl-2,2'-imino-bis(8hydroxyquinoline), Μ = Ge (5), Μ = Sn (6) are described. New stable linear or cyclic organometallic compounds and metallanethiones and -selones L 2 M=E ( Ε = S, Se ) are obtained starting from 1-4.
doi:10.1515/mgmc.1997.20.12.791
fatcat:oepvuz5m3zgaznwy5cm62ru4gu