Crystal structure of η6 -benzene(chloro)(N-[(5)-(-)1-phenylethyl]-thiobenzamidato)ruthenium(II), (C6H6)Ru(C15H14NS)Cl

H. Brunner, Th. Zwack, M. Zabel
2002 Zeitschrift für Kristallographie - New Crystal Structures  
C21H20CINR11S, orthorhombic, P2i2& (No. 19), a = 11.8187(5) Â, b = 16.1775(6) Â, c = 29.993(1) Â, V= 5734.5 Â 3 , Z= 12, R gl (F) = 0.037, wR^F 2 ) = 0.067, T= 173 K. Source of material 483 mg (2.00 mmol) of ^-[(5)-(-)l-phenylethyl]thiobenzamide [1, 2] were dissolved in CH2CI2 (20 ml) and cooled to 223 Κ [(?7 6 -benzene)RuCl2]2 (500 mg, 1.00 mmol) was added at this temperature. After stirring the mixture for 16 h while raising the temperature to r.t. the dark red solution was filtered through
more » ... lite and the solvent was removed. The brownish red residue was treated with an equimolar amount of KO'Bu in CH2CI2. The solvent was removed after 16 h and the residue was dissolved in a minimum amount of CHCI3. After chromatography on silica gel
doi:10.1524/ncrs.2002.217.jg.551 fatcat:actk4cwiivez5eifjzlgpfenzq