Three reversible states controlled on a gold monoatomic contact by the electrochemical potential

Manabu Kiguchi, Tatsuya Konishi, Kouta Hasegawa, Satoshi Shidara, Kei Murakoshi
2008 Physical Review B  
Conductance of an Au mono atomic contact was investigated under the electrochemical potential control. The Au contact showed three different behaviors depending on the potential: 1 G_0 (G_0 = 2e^2/h), 0.5 G_0 and not-well defined values below 1 G_0 were shown when the potential of the contact was kept at -0.6 V (double layer potential), -1.0 V (hydrogen evolution potential), and 0.8 V (oxide formation potential) versus Ag/AgCl in 0.1 M Na_2SO_4 solution, respectively. These three reversible
more » ... es and their respective conductances could be fully controlled by the electrochemical potential. These changes in the conductance values are discussed based on the proposed structure models of hydrogen adsorbed and oxygen incorporated on an Au mono atomic contact.
doi:10.1103/physrevb.77.245421 fatcat:kzpdv4zlnnclxge5jmuyy2tfiu