New Approaches to the Regioselective Synthesis of Heteroaryl Triflones

Xiu-Hua Xu, Norio Shibata
2013 Journal of Synthetic Organic Chemistry, Japan  
Heteroaryl tri ones are potential building blocks for the synthesis of novel biologically active compounds as well as functional materials. However, their synthesis has received relatively little attention. In this account, we describe our recent development of three novel synthetic strategies for the regioselective synthesis of heteroaryl tri ones: direct tri uoromethanesulfonylation of heteroaromatic compounds, anionic Fries rearrangement of heteroaryl tri ates, and transformation from tri yl
more » ... rmation from tri yl containing building blocks.
doi:10.5059/yukigoseikyokaishi.71.1195 fatcat:kr53tmljjnaj5gfanbiicilxpi