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In this paper, we investigate the polyvinylferrocene ͑PVF͒ redox behavior in contact with a bathing solution containing L-glutamine ͑Gln͒ by electrochemical quartz crystal microbalance ͑EQCM͒. Our study shows that the interaction of PVF with Gln is dramatically different from PVF redox behavior in salt solutions, e.g., NaClO 4 . Rather than the doping of anion in anodic process and undoping of anion in cathodic process, Gln doping and undoping are observed in either anodic or cathodic processdoi:10.1149/1.2048230 fatcat:t44olmvcvbe4jhiz2q22becf44