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THE FIRST ISOLATION OF LITHIUM PERFLUOROORGANOTRIMETHOXYBORATES Li [RFB(OMe)3] (RF = C2F5, CF2=CF AND C6F5) - THREE SAMPLES OF NEW CLASSES OF FLUOROORGANOBORON COMPOUNDS
2001
Main Group Metal Chemistry
Preserved Fulltext
The previously unknown classes of fluoroorganoboron compounds, lithium perfluoroorganotrimethoxyborates Li [R F B(OCH 3 ) 3 ] (R F = C 2 F 5 , CF 2 =CF and C 6 F 5 ), were prepared by the nucleophilic addition of R F Li to B(OCH 3 ) 3 in ether. The Li [R F B(OCH 3 ) 3 ] salts contain no ether coordinated at Li* and are stable at room temperature towards elimination. In solution they show a differentiated behaviour of protodeborylation.
doi:10.1515/mgmc.2001.24.12.845
fatcat:qrzaszbz2vd4xfjqrcnyhkj4ce