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Generation and Reactions of Inorganic Radicals with Special Reference to Carbonate Radicals
Department of Chemistry, Indian Institute of Technology, Madras-600 036 Methods of generation of a few inorganic radicals by irradiation are briefly reviewed and their properties discussed. The carbonate radical is dealt with in some detail. Its modes of reaction with several types of organic substrates, such as aromatic amines, aliphatic open chain amines and cyclic amines with bridgehead nitrogen atoms are discussed. Carbonate radical forms an adduct with anilines via electrophilic attack,doi:10.5281/zenodo.6326819 fatcat:mnxbexattnhjdfmpovazyrn5cm