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A zwitterionic triphosphenium compound as a tunable multifunctional donor
2016
Dalton Transactions
We present a zwitterionic triphosphenium molecule which features dicoordinate, tricoordinate and tetracoordinate phosphorus centers in addition to a cyclopentadienyl moiety. Crystallographic, computational, electrochemical and spectroscopic data illustrate and rationalize the reactivity of this molecule as a multifunctional ligand for both transition metals and main group acceptors and suggest how the donor properties may be tuned.
doi:10.1039/c5dt03915k
pmid:26647121
fatcat:lb2p4pllgfebvejvz6ffgrutry