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Unique molecular geometries of reduced 4- and 5-coordinate zinc complexes stabilised by diiminopyridine ligand
2016
Dalton Transactions
Stepwise reduction of the diiminopyridine complex dimpyrZnCl2 by KC8 leads to compounds dimpyrZnCl (2), dimpyrZnCl(DMAP) (3) and dimpyrZn(DMAP)2 (4) having unusual square-planar and see-saw geometries.
doi:10.1039/c6dt02001a
pmid:27488247
fatcat:up3nzkqbxvczhjikoiaaikz7i4