Kinetics of the Thermal Degradation of Granulated Scrap Tyres: a Model-free Analysis

Félix A. LÓPEZ, Amir A. EL HADAD, Francisco J. ALGUACIL, Teresa A. CENTENO, Belén LOBATO
2013 Medžiagotyra  
Pyrolysis is a technology with a promising future in the recycling of scrap tyres. This paper determines the thermal decomposition behaviour and kinetics of granulated scrap tyres (GST) by examining the thermogravimetric/derivative thermogravimetric (TGA/DTG) data obtained during their pyrolysis in an inert atmosphere at different heating rates. The model-free methods of Friedman, Flynn-Wall-Ozawa and Coats-Redfern were used to determine the reaction kinetics from the DTG data. The apparent
more » ... a. The apparent activation energy and pre-exponential factor for the degradation of GST were calculated. A comparison with the results obtained by other authors was made.
doi:10.5755/ fatcat:eowc4wbqdvfvtd6il32ygnrksi